Crystal structure of tetra­hydro­seselin, an angular pyran­ocoumarin

نویسندگان

  • A K Bauri
  • S Foro
  • A F M M Rahman
چکیده

In the title compound, tetra-hydro-seselin, C14H16O3, a pyran-ocoumarin [systematic name: 8,8-dimethyl-3,4,9,10-tetra-hydro-2H,8H-pyrano[2,3-f]chromen-2-one] obtained from the hydrogenation of seselin in the presence of Pd/C in MeOH at room temperature, the dihedral angle between the central benzene ring and the best planes of the outer fused ring systems are 6.20 (7) and 10.02 (8)°. In the crystal, mol-ecules show only very weak inter-molecular C-H⋯O inter-actions.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Crystal structure of a photobiologically active brominated angular pyran­ocoumarin: bromo-hy­droxy-seselin

The title compound, C14H13BrO3 [systematic name: rac-(9S,10R)-9-bromo-10-hy-droxy-8,8-dimethyl-9,10-di-hydro-2H,8H-pyrano[2,3-f]chromen-2-one], is a substituted pyran-ocoumarin, obtained by bromination of seselin [8,8-dimethyl-2H,8H-pyrano[2,3-f]chromen-2-one], which was isolated from the Indian herb Trachyspermum stictocarpum (Aajmod). The pyrano ring has a distorted half-chair conformation an...

متن کامل

Crystal structure of di­bromo­meth­oxy­seselin (DBMS), a photobiologically active pyran­ocoumarin

The title compound, C15H14Br2O4 [systematic name: rac-(9S,10R)-3,9-dibromo-10-methoxy-8,8-dimethyl-9,10-dihydropyrano[2,3-h]chromen-2(8H)-one], is a pyran-ocoumarin derivative formed by the bromination of seselin, which is a naturally occurring angular pyran-ocoumarin isolated from the Indian herb Trachyspermum stictocarpum. In the mol-ecule, the benzo-pyran ring system is essentially planar, w...

متن کامل

Redetermination of Crystal Structure of N,N'-bis (2-Hydroxybenzylidene)-2,2-Dimethyl-1,3-Propanediamine

The structure of N,N'-bis(2-hydroxybenzylidene)-2,2-dimethyl-1,3-propanediamine, C19H22N2O2, has been studied at low temperature (120K) by means of single-crystal X-ray diffraction. Solving the structure shows an orthorhombic unit cell, with P212121 space group, Z = 4, a = 6.1046 (4) Å, b = 15.8349 (11)</e...

متن کامل

A Compromise Decision-Making Model Based on TOPSIS and VIKOR for Multi-Objective Large- Scale Nonlinear Programming Problems with A Block Angular Structure under Fuzzy Environment

This paper proposes a compromise model, based on a new method, to solve the multiobjectivelarge scale linear programming (MOLSLP) problems with block angular structureinvolving fuzzy parameters. The problem involves fuzzy parameters in the objectivefunctions and constraints. In this compromise programming method, two concepts areconsidered simultaneously. First of them is that the optimal alter...

متن کامل

A New Compromise Decision-making Model based on TOPSIS and VIKOR for Solving Multi-objective Large-scale Programming Problems with a Block Angular Structure under Uncertainty

This paper proposes a compromise model, based on a new method, to solve the multi-objective large-scale linear programming (MOLSLP) problems with block angular structure involving fuzzy parameters. The problem involves fuzzy parameters in the objective functions and constraints. In this compromise programming method, two concepts are considered simultaneously. First of them is that the optimal ...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره 73  شماره 

صفحات  -

تاریخ انتشار 2017